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the well. At this point, the wave function 'spills over' the barriers, thus leading to an increase in Az. Interestingly, the minimum in Az Apz is just above the h/2 limit given by Heisenberg's Uncertainty Principle. This is perhaps even more dramatically illustrated by the curves shown in Fig. 3.26, which plots AzAp z versus the barrier mass for a variety of well widths. These data correspond to the single quantum well shown in Fig. 2.21, which at the point of introduction was thought to imply a violation of Heisenberg's Uncertainty Principle, but now, however, the calculations reveal this not to be the case. The non-monotonic behaviour as a function of well width is again apparent from the ordering of the curves for any particular mass. In addition, a non-monotonic behaviour as a function of the electron mass in the barrier can be seen. The minimum value of AzApz on Fig. 3.26 occurs for lw=50 A, as would be expected from earlier. This occurs for a barrier mass which is very close to the well mass of 0.067 mo and is equal to 0.508 h, which is very close, but still larger than h/2. 3.16 EXTENSION TO INCLUDE BAND NON-PARABOLICITY For semiconductor heterostructures with relatively low barrier heights and low carrier densities, the electrons cluster around the subband minima and their energy is in turn reasonably close to the bulk conduction band minima, i.e. within a couple of hundred .meV,compared to a bandgap of the order of 1.5 eV. In this region, the band minima,

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We have thus determined expressions el and e2, and conclude that { true }

both the bulk conduction band and the in-plane subband, can be described by a parabolic E-k curve, i.e. in the usual form:

where Ak is the set of antecedents of rule k. Alternatively, the product can be used to calculate rule firing strengths:

if x^y ' { x^y } z := y { z = x\y } n y^x * { y^x } z := x { z = x]y }

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where k can be read as a three-dimensional vector for the bulk, or as a two-dimensional in-plane vector |k X y | for a subband. However, in situations where the electrons are forced up to higher energies, by either large barrier heights and narrow wells, or in the case of very high carrier densities, equation (3.71) becomes more approximate. This is even more important for holes in the valence band. The approximation can be improved upon by adding addition terms into the polynomial expansion for the energy. For example, no matter how complex the band structure along a particular direction, it clearly has inversion symmetry and hence can always be represented by an expansion in even powers of k, if sufficient terms are included, i.e. the energy E can always be described by:

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{ z = x\y } . Exercise 10.11. Given are two variables x and y. It is required to update the values stored in these variables so that the value of x is at most the value of y. In other words, it is required to sort the values of x and y. Using ghost variables X and Y to record the initial values of x and y, formulate an appropriate precondition and postcondition and construct a conditional statement that implements the specification. Take care to specify that the initial values of x and y are not lost in the process of sorting. D Exercise 10.12. A program has two real variables x and y and one integer variable k. Initially, k is strictly positive. It is required to decrease the value of k to a positive value whilst maintaining the value of xk x y constant. Using ghost variable C to record the initial value of xk x y and ghost variable K to record the initial value of k, the precondition is

Usually when discussing single band models, as has been focused on entirely so far, the energy origin is set at the bottom of the band of interest, and thus ao = 0. In addition, truncating the series at k2, gives a = h2/(2m*}.

= F7

The next best approximation is to include terms in k4, hence accounting for band non-parabolicity, as displayed in Fig. 3.27, with:

and the postcondition is (Observe how the combination of the conjunct k = K in the precondition and the conjunct k < K in the postcondition express the requirement that k is decreased.) It is of course always possible to decrease k by subtracting 1. When k is even, however, it is possible to decrease it at least as much, and generally more, by dividing by 2. So, we are interested in constructing expressions a, b, c and d such that if true ' k,x,3> := k-l,a,b

then clearly m* remains a function of K, unlike the case of parabolic bands where it is a constant. As it is a function of k, then it is also a function of energy, and indeed band non-parabolicity is accounted for by allowing the effective mass to have an energy dependence [64]: where V is the barrier height and the parameter o; is given by [65,66]:

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